Valentine’s Day came early as Hollywood’s finest emerged on Grauman’s Chinese Theatre for the premiere of “Valentine’s Day.”

Actors from the all-star line-up, which includes half of Tinseltown, hit the red carpet in Hollywood last night for the premiere of romantic comedy, “Valentines Day.”

Anne Hathaway gave her thoughts on the most romantic day of the year saying, “I usually forget that it’s coming, but then I celebrate it in style,” Hathaway mused. “I think the whole day meant to be fun and if you hate it then you’re taking it too seriously.”

Love was in the air as the cast of lovely ladies came out in an array of dazzling dresses and romantic gowns, and the men didn’t look so bad themselves.

Jessica Biel led the way in the fashion department in a Pre-Fall 2010 Oscar de la Renta pink chiffon one-shoulder.

The 27-year-old star was a vision of beauty in the feminine confection, which was full of voluminous layers of flowing chiffon in pink and white. I’ve never seen Biel in such a romantic look and absolutely loved it. She paired the gown with pale pink Christian Louboutin heels and matching lipstick. SIMPLY STUNNING!

Demi Moore, 47, who accompanied her husband Ashton Kutcher, kept it simple yet elegant with a white Chanel Spring 2010 Haute Couture dress. The strapless frock had a classic shape, but upon closer inspection the spectacular textured fabric and chiffon petal appliqués was revealed.

She paired this fabulous look with simple black Brian Atwood “Maniac” pumps, a Roger Vivier clutch and Chanel jewels.

Jennifer Garner’s wore a show-stopping little black Valentino Pre-Fall 2010 dress that was a work of art in itself. Jen’s edgy look was a surprise considering her previous red carpet picks, but she owned the look and was smashing.

The strapless frock, a mix of leather and beaded lace panels, had nude illusion cut-outs and delicate lace that wrapped around the bodice. Garner kept her accessories simple with black Brian Atwood “Maniac” pumps, but pumped up the volume with her voluminous hair. .

Completing the cutting edge look, Jennifer Garner’s soft tousled tresses, courtesy of Frederic Fekkai celebrity stylist Adir Abergel, was the perfect finishing touch.

Jessica Alba, 28, stood out in a bold Proenza Schouler Spring 2010 minidress with green peacock feathers and intricate beaded detailing.

Paired with chunky Marc Jacobs Resort 2010 platform shoes, the bold color choice and unique design was a refreshing addition to the red carpet. The only place Jessica failed was with her hair. Showing off her newly cropped hairdo, Jessica went for an unkempt look that ended up looking wet and messy.

Showing that great style (and good looks) runs in the family actress Julia Roberts attended the premiere with her niece, Emma Roberts, who also appears in the movie.

The dynamic duo looked radiant as they hit the red carpet hand-in-hand in a fantastic selection of dresses: Christian Dior Resort 2010 for Julia and Jenny Packham Spring 2010 for Emma.

Roberts selected the perfect black organza dress, with fold-over waist and embroidered details.

Emma kept things fun and flirty in a crystal encrusted mini halter dress and Brian Atwood silver “Kendall” shoes.

Last but not least, Anne Hathaway, 27, wore a sapphire Marchesa feathered cocktail dress.

Showing off her lengthy legs, Hathaway accessories with Casadei platforms, Georgina Chapman for Garrard earrings in addition to a Roger Viver black jewel encrusted clutch.

One notable absence was cast member Taylor Swift, who recently split with boyfriend and co-star Taylor Lautner.

The “Valentine’s Day” filmmakers managed to secure an ensemble cast of stars, almost all of whom made an appearance at the Hollywood premiere.

Cast members for the new film include Jessica Alba, Julia Roberts, Ashton Kutcher, Jessica Biel, Bradley Cooper, Patrick Dempsey, Jennifer Garner, Eric Dane, Queen Latifah, Taylor Lautner, Taylor Swift and Anne Hathaway.

The romantic comedy follows the intertwining storylines of a group of couples based in Los Angeles. And there is already a sequel on the way with director Garry Marshall and screenwriter Katherine Fugate returning to steer the follow-up, entitled New Year’s Eve and will take place in New York City as the clock ticks over to January 1.

Several members of the Valentine’s Day cast will be back for the new film.

More photos below